Publications

2020

Nishani K Jayakody, Carla C. Fraenza, Steven G. Greenbaum, David S. Ashby, and Bruce S. Dunn, "NMR Relaxometry and Diffusometry Analysis of Dynamics in Ionic Liquids and Ionogels for Use in Lithium Ion Batteries" Journal of Physical Chemistry B, 2020.
DOI: 10.1021/acs.jpcb.0c02755

Brian Chen, Sarah Mitchell, Nicholas Sinclair, Jesse Wainright, Emily Pentzer and Burcu Gurkan, "Feasibility of TEMPO-functionalized imidazolium, ammonium and pyridinium salts as redox-active carriers in ethaline deep eutectic solvent for energy storage", Molecular Systems Design and Engineering, 2020.
DOI: 10.1039/D0ME00038H

Jeffrey M. Klein, Henry Squire, William Dean, and Burcu E. Gurkan, "From Salt in Solution to Solely Ions – Solvation of MethylViologen in Deep Eutectic Solvents and Ionic Liquids", Journal of Physical Chemistry B, 2020.
DOI: 10.1021/acs.jpcb.0c03296

Yong Zhang, Derrick Poe, Luke Heroux, Henry Squire, Brian W. Doherty, Zhuoran Long,Mark Dadmun, Burcu Gurkan, Mark E. Tuckerman, and Edward J. Maginn, "Liquid Structure and Transport Properties of the Deep EutecticSolvent Ethaline", Journal of Physical Chemistry B, 2020.
DOI: 10.1021/acs.jpcb.0c04058

Miomir B. Vukmirovic, Radoslav R. Adzic, and Rohan Akolkar, "Copper Electrodeposition from Deep Eutectic Solvents – Voltammetric Studies Providing Insights into the Role of Substrate: Platinum vs. Glassy Carbon", Journal of Physical Chemistry B, 2020.
DOI: 10.1021/acs.jpcb.0c02735

X. Shen, N. Sinclair, J. Wainright, R. Akolkar, and R.F. Savinell, "Evaluating and developing a reliable reference electrode for choline chloride based deep eutectic solvents", Journal of the Electrochemical Society, 2020 167 (8).
DOI: 10.1149/1945-7111/ab913c

Guanhe Rim, Ariane Katrina Marchese, Phillip Stallworth, Steven G. Greenbaum, Ah-Hyung Alissa Park, "29 Si Solid State MAS NMR Study on Leaching Behaviors and Chemical Stability of Different Mg-Silicate Structures CO2 Sequestration", Chemical Engineering Journal, 396 (c). 
DOI: 10.1016/j.cej.2020.125204

L. Chang and A. J. Bard, "Electrochemical Characterization of Bromine Reduction to Tribromide in Individual Nitrobenzene-in-Water Emulsion Droplets",  Journal of The Electrochemical Society, 2020 167 (6).
DOI: 10.1149/1945-7111/ab80ab

Nora A. Shaheen, Ijjada Mahesh, Miomir B. Vukmirovic, Rohan Akolkar, "Hysteresis effects and roughness suppression efficacy of polyethylenimine additive in Cu electrodeposition in ethaline",  Electrochemistry Communications 2020 115 106721
DOI: 10.1016/j.elecom.2020.106721

2019

J.M. Klein; H. Squire; B. Gurkan Electroanalytical Investigation of the Electrode–Electrolyte Interface of Quaternary Ammonium Ionic Liquids: Impact of Alkyl Chain Length and Ether Functionality, The Journal of Physical Chemistry C, (2019).
DOI: 10.1021/acs.jpcc.9b08016

Dai Shen, Miomir B Vukmirovic, Rohan Akolkar, "Understanding the Role of Complexation in the Charge-Transfer Kinetics of the Cu2+ + e ↔ Cu1+ Redox Reaction in Ethaline Deep Eutectic Solvent", Journal of The Electrochemical Society, 166 (15), E526-E532 (2019)
DOI: 10.1149/2.1211915jes

Burcu Gurkan, Henry Squire, and Emily Pentzer, "Metal-Free Deep Eutectic Solvents: Preparation, Physical Properties, and Significance", The Journal of Physical Chemistry Letters 2019 10 (24), 7956-7964
DOI: 10.1021/acs.jpclett.9b01980

2018

Dai Shen, Katherine Steinberg, Rohan Akolkar, “Avoiding Pitfalls in the Determination of Reliable Electrochemical Kinetics Parameters for the Cu2+→Cu1+ Reduction Reaction in Deep Eutectic Solvents”, Journal of The Electrochemical Society , 165 (14), E808-E815, 2018,
DOI: 10.1149/2.1011814jes