Publications

2021

Mounesha N. Garaga, Nishani Jayakody, Carla C. Fraenza, Boris Itin, Steven Greenbaum, "Molecular-level insights into structure and dynamics in ionic liquids and polymer gel electrolytes", Journal of Molecular Liquids, 2021.
DOI: 10.1016/j.molliq.2021.115454

Guanhe Rim,   Noyonika Roy,   Diandian Zhao,   Shiho Kawashima,   Phillip E. Stallworth,   Steve G. Greenbaum  and  Ah-Hyung Alissa Park   , "CO2 Utilization in Built Environment via the PCO2 Swing Carbonation of Alkaline Solid Wastes with Different Mineralogy", Faraday Discussions, 2021.
DOI: 10.1039/D1FD00022E

Md Ashraful Haque, Tony G. Feric, Sara T. Hamilton, Ah-Hyung Alissa Park, Mark D. Dadmun, "Structure and Dispersion of Free and Grafted Polymer in Nanoparticle Organic Hybrid Materials-based Solutions by Small Angle Neutron Scattering", The Journal of Physical Chemistry C, 2021.
DOI: 10.1021/acs.jpcc.0c10790

Emmanuel Urandu Mapesa, Nelly M. Cantillo, Sara Triana Hamilton, Matthew A. Harris, Thomas A. Zawodzinski Jr., Ah-Hyung Alissa Park, Joshua Sangoro, "Localized and Collective Dynamics in liquid-like Polyethylenimine-based Nanoparticle Organic-Inorganic Hybrid Materials", Macromolecules, 2021.
DOI: 10.1021/acs.macromol.0c02370

Nicholas S. Sinclair, Derrick Poe, Robert F. Savinell, Edward J. Maginn, Jesse S. Wainright, "A Nitroxide Containing Organic Molecule in a Deep Eutectic Solvent for Flow Battery Applications ", J. Electrochem. Soc. , 2021.
DOI: 10.1149/1945-7111/abe28a

William Dean, Jeffrey Klein and Burcu Gurkan, "Do Deep Eutectic Solvents Behave Like Ionic Liquid Electrolytes? A Perspective from the Electrode-Electrolyte Interface2" Journal of The Electrochemical Society, 2021.
DOI: 10.1149/1945-7111/abde83

2020

Yun-Yang Lee, Drace Penley, Aidan Klemm, William Dean, and Burcu Gurkan, "Deep Eutectic Solvent Formed by Imidazolium Cyanopyrrolide and Ethylene Glycol for Reactive CO 2 Separations" ACS Sustainable Chemistry Engineering, 2020.
DOI: 10.1021/acssuschemeng.0c07217

Hansen, B. B.; Spittle, S.; Chen, B.; Poe, D.; Zhang, Y.; Klein, J. M.; Horton, A.; Adhikari, L.; Zelovich, T.; Doherty, B. W.; Gurkan, B.; Maginn, E. J.; Ragauskas, A.; Dadmun, M.; Zawodzinski, T. A.; Baker, G. A.; Tuckerman, M. E.; Savinell, R. F.; Sangoro, J. R., "Deep Eutectic Solvents: A Review of Fundamentals and Applications", Chemical Review, 2020.
DOI: 10.1021/acs.chemrev.0c00385

Nora A. Shaheen,Mahesh Ijjada, Miomir B. Vukmirovic, and Rohan Akolkar, "Mechanism of Electrochemical Oxidation of Nitroxide Radicals in Ethaline Deep Eutectic Solvent" J. Electrochem. Soc., 2020.
DOI: 10.1149/1945-7111/abc439

Jing Peng, Nelly M. Cantillo, K. McKensie Nelms, Lacey S. Roberts, Gabriel Goenaga, Adam Imel, Brian Andrew Barth, Mark Dadmun, Luke Heroux, Douglas G. Hayes, and Thomas Zawodzinski, "Electron Transfer in Microemulsion-Based Electrolytes" ACS Applied Materials and Interfaces, 2020.
DOI: 10.1021/acsami.0c07028

Nelly M. Cantillo, Maria Bruce, Sara T. Hamilton, Tony G. Feric, Ah-Hyung Alissa Park and Thomas A. Zawodzinski Jr., "Electrochemical Behavior of Copper Ion Complexed with Nanoparticle Organic Hybrid Materials" IOP Science, 2020.
DOI: 10.1149/1945-7111/aba158

Nishani K Jayakody, Carla C. Fraenza, Steven G. Greenbaum, David S. Ashby, and Bruce S. Dunn, "NMR Relaxometry and Diffusometry Analysis of Dynamics in Ionic Liquids and Ionogels for Use in Lithium Ion Batteries" Journal of Physical Chemistry B, 2020.
DOI: 10.1021/acs.jpcb.0c02755

Brian Chen, Sarah Mitchell, Nicholas Sinclair, Jesse Wainright, Emily Pentzer and Burcu Gurkan, "Feasibility of TEMPO-functionalized imidazolium, ammonium and pyridinium salts as redox-active carriers in ethaline deep eutectic solvent for energy storage", Molecular Systems Design and Engineering, 2020.
DOI: 10.1039/D0ME00038H

Jeffrey M. Klein, Henry Squire, William Dean, and Burcu E. Gurkan, "From Salt in Solution to Solely Ions – Solvation of MethylViologen in Deep Eutectic Solvents and Ionic Liquids", Journal of Physical Chemistry B, 2020.
DOI: 10.1021/acs.jpcb.0c03296

Yong Zhang, Derrick Poe, Luke Heroux, Henry Squire, Brian W. Doherty, Zhuoran Long,Mark Dadmun, Burcu Gurkan, Mark E. Tuckerman, and Edward J. Maginn, "Liquid Structure and Transport Properties of the Deep EutecticSolvent Ethaline", Journal of Physical Chemistry B, 2020.
DOI: 10.1021/acs.jpcb.0c04058

Miomir B. Vukmirovic, Radoslav R. Adzic, and Rohan Akolkar, "Copper Electrodeposition from Deep Eutectic Solvents – Voltammetric Studies Providing Insights into the Role of Substrate: Platinum vs. Glassy Carbon", Journal of Physical Chemistry B, 2020.
DOI: 10.1021/acs.jpcb.0c02735

X. Shen, N. Sinclair, J. Wainright, R. Akolkar, and R.F. Savinell, "Evaluating and developing a reliable reference electrode for choline chloride based deep eutectic solvents", Journal of the Electrochemical Society, 2020 167 (8).
DOI: 10.1149/1945-7111/ab913c

Guanhe Rim, Ariane Katrina Marchese, Phillip Stallworth, Steven G. Greenbaum, Ah-Hyung Alissa Park, "29 Si Solid State MAS NMR Study on Leaching Behaviors and Chemical Stability of Different Mg-Silicate Structures CO2 Sequestration", Chemical Engineering Journal, 396 (c). 
DOI: 10.1016/j.cej.2020.125204

L. Chang and A. J. Bard, "Electrochemical Characterization of Bromine Reduction to Tribromide in Individual Nitrobenzene-in-Water Emulsion Droplets",  Journal of The Electrochemical Society, 2020 167 (6).
DOI: 10.1149/1945-7111/ab80ab

Nora A. Shaheen, Ijjada Mahesh, Miomir B. Vukmirovic, Rohan Akolkar, "Hysteresis effects and roughness suppression efficacy of polyethylenimine additive in Cu electrodeposition in ethaline",  Electrochemistry Communications 2020 115 106721
DOI: 10.1016/j.elecom.2020.106721

2019

J.M. Klein; H. Squire; B. Gurkan Electroanalytical Investigation of the Electrode–Electrolyte Interface of Quaternary Ammonium Ionic Liquids: Impact of Alkyl Chain Length and Ether Functionality, The Journal of Physical Chemistry C, (2019).
DOI: 10.1021/acs.jpcc.9b08016

Dai Shen, Miomir B Vukmirovic, Rohan Akolkar, "Understanding the Role of Complexation in the Charge-Transfer Kinetics of the Cu2+ + e ↔ Cu1+ Redox Reaction in Ethaline Deep Eutectic Solvent", Journal of The Electrochemical Society, 166 (15), E526-E532 (2019)
DOI: 10.1149/2.1211915jes

Burcu Gurkan, Henry Squire, and Emily Pentzer, "Metal-Free Deep Eutectic Solvents: Preparation, Physical Properties, and Significance", The Journal of Physical Chemistry Letters 2019 10 (24), 7956-7964
DOI: 10.1021/acs.jpclett.9b01980

2018

Dai Shen, Katherine Steinberg, Rohan Akolkar, “Avoiding Pitfalls in the Determination of Reliable Electrochemical Kinetics Parameters for the Cu2+→Cu1+ Reduction Reaction in Deep Eutectic Solvents”, Journal of The Electrochemical Society , 165 (14), E808-E815, 2018,
DOI: 10.1149/2.1011814jes